Adam speaks in Genesis 2:23 and 3:10,12. Eve speaks in Genesis 3:3,13 and 4:1,25.
The first is between Adam and Eve in Genesis 2:21-25 and the last is Jesus to His bride (the Church) in Revelation 19:7-8 and 21:2.
Read Genesis 2:16–17.
First to Adam and Eve in Genesis 1:28, second to Noah and his sons in Genesis 9:1,7, and finally to Jacob in Genesis 35:11.